[nilesh]

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Hi buddy as I want to do M.Sc. (Chemistry) form Maharshi Dayanand University (MDU), Rohtak , so would you plz provide me its syllabus to do compare it with other universities syllabus ??

[Vishal Kotkar]

As you want here I am providing Maharshi Dayanand University (MDU), Rohtak M.Sc. (Chemistry) program syllabus :


M.Sc. Chemistry Ist Semester
Paper I CH-401 Inorganic Chemistry
4 hrs. / Week
Max. Marks: 80
Time: 3 Hrs.
Note:-Examiner will set 09 questions and the candidates will be required to attempt 05
questions in all. Out of 09 questions one question will be compulsory containing 08 short
answer type questions covering the entire syllabus. Further, examiner will set 02
questions from each section and the candidates will be required to attempt one question
from each section. All questions will carry equal marks.
Section-A
Stereochemistry and Bonding in Main Group compounds: VSEPR theory, dπ -pπ
bonds, Bent rule and energetic of hybridization.
(7 Hrs.)
Metal-Ligand Equilibria in solution
Stepwise and overall formation constants and their interactions, trends in stepwise
constants, factors affecting stability of metal complexes with reference to the nature of
metal ion and ligand, chelate effect and its thermodynamic origin, determination of
binary formation constants by pH-metry and spectrophotometry.
(8 Hrs.)
Section-B
Reaction Mechanism of Transition Metal Complexes-I
Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation
of complexes from aquo ions, Ligand displacement reactions in octahedral complexes-
acid hydrolysis, Base hydrolysis, racemization of tris chelate complexes, electrophilic
attack on ligands.
(15 Hrs.)
Section-C
Reaction Mechanism of Transition Metal Complexes-II
Mechanism of ligand, displacement reactions in square planar complexes, the trans effect,
theories of trans effect, mechanism of electron transfer reactions – types; outer sphere
electron transfer mechanism and inner sphere electron transfer mechanism, electron
exchange.
(15 Hrs.)
Section-D
Isopoly and Heteropoly Acids and Salts
Isopoly and Heteropoly acids and salts of Mo and W: Structures of isopoly
and heteropoly anions.
(7 Hrs.)
Crystal Structures
Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile,
antirutile, crystobalite, layer lattices- Cd I2, Bi I3; Re O3, Mn2O3, corundum, pervoskite,
Ilmenite and Calcite.
( 8 Hrs.)

Maharshi Dayanand University (MDU), Rohtak M.Sc. (Chemistry) program syllabus