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I want to do M.Sc Chemisrty from Mumbai University so can you please tell me the syllabus of Msc Chemistry of this University?

[Vishal Kotkar]

Ok, I am providing you the syllabus of Msc Chemistry of Mumbai University.

Mumbai University Msc Chemistry syllabus

SEMESTER I

Course Code –(Physical Chemistry) PSCH 101

Total Lectures 60 L]

Unit - I

Topic - Thermodynamics-I

1.1 State function and exact differentials. Maxell equations, Maxwell thermodynamic
square, Joule Thomson experiment, Joule Thomson coefficient, inversion temperature,
Joule Thomson coefficient in terms of van der Waals constants, Temperature
dependence of enthalpy and entropy , Gibbs energy of reaction

1.2 Third law of Thermodynamics, Entropy change for a phase transition, absolute
entropies, determination of absolute entropies in terms of heat capacity data, standard
molar entropies and their dependence on molecular mass and molecular structure.
Residual entropy.
[10 ]

Unit-II

Topic - Thermodynamics-II
[15L]

2.1 Fugacity of real gases, Determination of fugacity of real gases using
graphical method and from equation of state. Equilibrium constant for real gases in
terms of fugacity.
Gibbs energy of mixing, entropy and enthalpy of mixing.
[4 L]

2.2 Real solutions: Chemical potential in non ideal solutions excess functions of non ideal
solutions calculation of partial molar volume and partial molar enthalpy, Gibbs Duhem
Margules equation.
[6 L]

2.3 Applications of thermodynamic functions to life processesEntropy and free energy
changes of a biochemical reaction, Free energy changes involved in reactions that
synthesize and utilize ATP.
[5L]

Unit-III

Topic - Applied Thermodynamics

3.1 Two component system

(Solid –Gas System) I-Hydrate formation II- Amino compound formation
[2L]
(Solid – Liquid System) I – Formation of a compound with congruent melting point
II- Formation of a compound with incongruent melting point
[2L]

3.2 Three component system
Recapitulation: Graphical representation of three component system; system of
three liquids: having partial miscibility.
Type-I Formation of one pair of partially miscible liquids
Type-II Formation of two pairs of partially miscible liquids
Type-III Formation of three pairs of partially miscible liquids
[2L]

3.3 Ternary system of two solid compounds and one liquid

1. Double salt formation – (a) Double salt not decomposed by water
H2O – AgNO3 – NH4NO3
(b) Double salt decomposed by water
H2O –AgNO3- KNO3 [2L]

2. One salt forming a hydrate – (a) Hydrate not dehydrated by second salt
H2O- Na2SO4 – NaCl
(Hydrate Na2So4,10 H2O is formed )
(b) Hydrate dehydrated by second salt.
H2O- Na2SO4- NaCl
(Na2SO4 is dehydrated by addition of NaCl) [2L]

3. Double salt forming hydrate –(a) Hydrated double salt not decomposed
by water (Alums stable in presence of water)
(b) Hydrated double salt decomposed by water [1L]

3.4 Thermodynamics of surfaces, Pressure difference across curved surface
(Laplace equation), vapour pressure of droplets (Kelvin equation), Gibbs adsorption
isotherm,BET isotherm (derivations expected).




For complete syllabus here is the attachment



Contact-

Mumbai University (MU)
Kalina, Santacruz East, Mumbai, Maharashtra 400098