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syllabus of msc chemistry in mumbai university |
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Re: syllabus of msc chemistry in mumbai university
Ok, I am providing you the syllabus of Msc Chemistry of Mumbai University. Mumbai University Msc Chemistry syllabus SEMESTER I Course Code –(Physical Chemistry) PSCH 101 Total Lectures 60 L] Unit - I Topic - Thermodynamics-I 1.1 State function and exact differentials. Maxell equations, Maxwell thermodynamic square, Joule Thomson experiment, Joule Thomson coefficient, inversion temperature, Joule Thomson coefficient in terms of van der Waals constants, Temperature dependence of enthalpy and entropy , Gibbs energy of reaction 1.2 Third law of Thermodynamics, Entropy change for a phase transition, absolute entropies, determination of absolute entropies in terms of heat capacity data, standard molar entropies and their dependence on molecular mass and molecular structure. Residual entropy. [10 ] Unit-II Topic - Thermodynamics-II [15L] 2.1 Fugacity of real gases, Determination of fugacity of real gases using graphical method and from equation of state. Equilibrium constant for real gases in terms of fugacity. Gibbs energy of mixing, entropy and enthalpy of mixing. [4 L] 2.2 Real solutions: Chemical potential in non ideal solutions excess functions of non ideal solutions calculation of partial molar volume and partial molar enthalpy, Gibbs Duhem Margules equation. [6 L] 2.3 Applications of thermodynamic functions to life processesEntropy and free energy changes of a biochemical reaction, Free energy changes involved in reactions that synthesize and utilize ATP. [5L] Unit-III Topic - Applied Thermodynamics 3.1 Two component system (Solid –Gas System) I-Hydrate formation II- Amino compound formation [2L] (Solid – Liquid System) I – Formation of a compound with congruent melting point II- Formation of a compound with incongruent melting point [2L] 3.2 Three component system Recapitulation: Graphical representation of three component system; system of three liquids: having partial miscibility. Type-I Formation of one pair of partially miscible liquids Type-II Formation of two pairs of partially miscible liquids Type-III Formation of three pairs of partially miscible liquids [2L] 3.3 Ternary system of two solid compounds and one liquid 1. Double salt formation – (a) Double salt not decomposed by water H2O – AgNO3 – NH4NO3 (b) Double salt decomposed by water H2O –AgNO3- KNO3 [2L] 2. One salt forming a hydrate – (a) Hydrate not dehydrated by second salt H2O- Na2SO4 – NaCl (Hydrate Na2So4,10 H2O is formed ) (b) Hydrate dehydrated by second salt. H2O- Na2SO4- NaCl (Na2SO4 is dehydrated by addition of NaCl) [2L] 3. Double salt forming hydrate –(a) Hydrated double salt not decomposed by water (Alums stable in presence of water) (b) Hydrated double salt decomposed by water [1L] 3.4 Thermodynamics of surfaces, Pressure difference across curved surface (Laplace equation), vapour pressure of droplets (Kelvin equation), Gibbs adsorption isotherm,BET isotherm (derivations expected). For complete syllabus here is the attachment Contact- Mumbai University (MU) Kalina, Santacruz East, Mumbai, Maharashtra 400098 |
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